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INTOCHEMISTRY · GENERAL CHEMISTRY

Net Ionic Equations & Precipitation

Identify dissolved spectators and write correctly balanced net ionic equations.

Step-by-step lessonWorked exampleInteractive practiceFree PDF + Word worksheet
Chemical reactions

Learn the concept, then practice it

Identify dissolved spectators and write correctly balanced net ionic equations. Start with the illustrated overview, follow the calculation, and try the questions.

Instructional diagram for Net Ionic Equations & Precipitation
Original IntoChemistry teaching diagram · Editable SVG also included in the package
Key relationship

molecular → complete ionic → cancel spectators → net ionic

01

Decide what dissolves

Use solubility guidelines to determine which products remain aqueous and which form a precipitate; nitrates and alkali-metal salts are generally soluble.

02

Separate only strong electrolytes

In complete ionic equations, split soluble ionic compounds into ions. Do not split solids, liquids, gases, or weak electrolytes.

03

Check atoms and charge

Cancel spectator ions and verify that both atoms and overall electric charge balance.

WORKED EXAMPLE

Mix aqueous AgNO₃ and NaCl. Write the net ionic equation.

AgNO₃(aq) + NaCl(aq) → AgCl(s) + NaNO₃(aq). Dissociate the soluble salts and cancel Na⁺ and NO₃⁻.

Final answer: Ag⁺(aq) + Cl⁻(aq) → AgCl(s)
!

Common mistake

A solid precipitate stays intact in an ionic equation. Cancelling a reacting ion is not allowed.

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